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. 2020 Sep 22;10(58):35109–35120. doi: 10.1039/d0ra07472a

Reaction of the cyclic vinyl phosphordiamidate 2h with phenyllithium and phenylmagnesium chloride.

graphic file with name d0ra07472a-u2.jpg
Entry M Temp. [°C] 5aa [%] 6a [%]
1 MgCl −78 to 23 36 33
2 MgCl −40 24 8
3 MgClb 0 to 23 25 45
4 Li −78 to 23 67 0
a

Isolated yield.

b

10 mol% of CuI was used as a catalyst.