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. 2020 Nov 4;10(66):40068–40083. doi: 10.1039/d0ra07587f

Gelation properties of the carbamate derivativesa.

No. Structures of R: Pump oil Tol i-PrOH EtOH EG Glycerol H2O EtOH : H2O (1 : 1) EtOH : H2O (1 : 2) DMSO : H2O (1 : 1) DMSO : H2O (1 : 2)
9 graphic file with name d0ra07587f-u1.jpg P GP P P P GO 20.0 I P P P GO 20.0
10 graphic file with name d0ra07587f-u2.jpg GT 20.0 S P P P P GP GP GP P GP
11 graphic file with name d0ra07587f-u3.jpg GT 20.0 S P S GO 20.0 GT 20.0 P GP GP GO 20.0 GO 20.0
12 graphic file with name d0ra07587f-u4.jpg GO 10.0 Go 20.0 S S P I I GT 20.0 GO 20.0 GO 10.0 P
13 graphic file with name d0ra07587f-u5.jpg GO 5.0 S S S P GO 20.0 I GO 10.0 GO 10.0 GO 20.0 GO 20.0
14 graphic file with name d0ra07587f-u6.jpg GO 5.0 S S S GO 10.0 I I GO 10.0 GO 5.0 GO 10.0 I
15 graphic file with name d0ra07587f-u7.jpg GT 5.0 P P P GP S P P P P I
16 graphic file with name d0ra07587f-u8.jpg I S S S I S I GO 5.0 GO 3.3 GO 6.7 I
17 graphic file with name d0ra07587f-u9.jpg I GC 20.0 P P S P I GO 2.5 GO 2.5 GO 10.0 GO 10.0
18 graphic file with name d0ra07587f-u10.jpg GT 20.0 P GO 10.0 P GO 10.0 GC 6.7 I GO 4.0 GO 10.0 GO 2.5 GO 3.3
19 graphic file with name d0ra07587f-u11.jpg P I S P S S GP 6.7 S GP S S
20 graphic file with name d0ra07587f-u12.jpg I GO 2.8 GC 10.0 GC 20.0 P GO 20.0 I GO 3.3 GO 2.5 Go 4.0 GO 2.8
21 graphic file with name d0ra07587f-u13.jpg I GC 20.0 P P P P I I I P P
22 graphic file with name d0ra07587f-u14.jpg I P P P P I I I P P P
23 graphic file with name d0ra07587f-u15.jpg I P S S P I I P P P P
24 graphic file with name d0ra07587f-u16.jpg GT 20.0 I I GP P S I GP GP P GT 6.7
25 graphic file with name d0ra07587f-u17.jpg I I GP GP GT 20.0 I I GP P I GP
26 graphic file with name d0ra07587f-u18.jpg GT 10.0 GP P P P S I I I P P
27 graphic file with name d0ra07587f-u19.jpg I GP GP P P S I I I P I
a

G, gel at room temperature, the numbers are the corresponding minimum gelation concentrations (MGCs) in mg mL−1; GC, clear or transparent gel; GT, translucent gel; GO, opaque gel; GP, partial gel at 20 mg mL−1 unless otherwise specified; I, insoluble; P, crystallize or precipitate; S, soluble at ∼20 mg mL−1.