Previously reported nanoscale catalytic systems based on the Ag element, applied for the conversion of the NB derivatives to their aniline analogues.
| Entry | Catalyst | Condition | Cat. amounta (mg) | Time (min) | Conversion (%) | Ref. |
|---|---|---|---|---|---|---|
| 1 | Ag–Ni core/shell NPs | 80 °C, KOH, IPAb | 50 | 150 | 95 | 72 |
| 2 | Ag–rGOc composite | Visible light irradiation | 50 | 240 | 98 | 73 |
| 3 | Ag–MPTA-1d composite | 80 °C, NaOH, under N2 | 250 | 600 | 97 | 74 |
| 4 | Ag–SBA-15e composite | NaBH4, r.t. | 10 | 6 | 95 | 75 |
| 5 | Ag–mNCf composite | NaBH4, r.t. | 5 | 150 | 97 | 76 |
| 6 | Ag–VP/CTSg composite | N2H4·H2O, 70 °C | 30 | 5 | 95 | — |
Per 1.0 mmol of the NB compound.
Isopropyl alcohol (IPA).
Reduced graphene oxide.
Poly-triallylamine (MPTA-1).
SBA-15 is a mesoporous silica.
Mesoporous melamine-N-doped carbon (mNC).
This work.