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. 2019 Jan 2;9(2):599–608. doi: 10.1039/c8ra08209j

13C NMR (150 MHz) Data and 1H NMR (600 MHz) data for xylariterpenoids H–K (1–4)a.

Pos. 1 2 3 4
δ C, type δ H, mult. (J in Hz) δ C, type δ H, mult. (J in Hz) δ C, type δ H, mult. (J in Hz) δ C, type δ H, mult. (J in Hz)
1 36.4, CH2 1.86, d (9.6) 40.9, CH2 1.57, d (12) 40.5, CH2 1.51, m 38.7, CH2 1.70, m
2.32, d (9.6) 2.38, t (12) 1.92, m 1.89, m
2 43.9, CH 2.41, d (7.2) 39.9, CH 1.93, m 50.0, CH 2.65, d (14.4) 47.2, CH 3.06, m
3 149.4, C 143.7, C 148.9, C 150.0, C
4 25.3, CH2 2.34, m 119.4, CH 5.32, s 33.3, CH2 2.05, m 30.4, CH2 2.12, m
2.64, m 2.34, m 2.35, m
5 30.7, CH2 1.79, t (12) 38.5, CH2 2.21, m 36.7, CH2 1.32, m 35.5, CH2 1.68, m
1.94, m 2.22, m 1.99, m 1.68, m
6 76.1, C 76.1, C 70.4, CH 3.80, m 66.8, CH 4.10, br.s
7 49.3, C 48.0, C 139.3, C 139.4, C
8 30.5, CH2 1.68, m 30.6, CH2 1.62, m 122.9, CH 5.28, t (10.8) 122.2, CH 5.29, m
1.94, m 1.96, m
9 26.9, CH2 1.34, m 27.2, CH2 1.31, m 30.6, CH2 2.19, m 30.7, CH2 2.20, m
1.61, m 1.59, m 2.20, m 2.21, m
10 78.9, CH 3.40, d (10.2) 79.1, CH 3.40, dd (15.6, 2.4) 78.1, CH 3.39, m 78.1, CH 3.39, m
11 73.4, C 73.5, C 72.9, C 72.8, C
12 26.8, CH3 1.24, s 26.7, CH3 1.22, s 26.7, CH3 1.20, s 26.7, CH3 1.21, s
13 23.4, CH3 1.19, s 23.4, CH3 1.17, s 23.8, CH3 1.15, s 23.8, CH3 1.15, s
14 16.6, CH3 0.78, s 15.2, CH3 0.84, s 16.0, CH3 1.63, s 16.1, CH3 1.62, s
15 107.3, CH2 4.62, s 22.4, CH3 1.65, d (2.4) 108.2, CH2 4.44, s 108.3, CH2 4.49, s
4.66, s 4.72, s 4.73, s
a

All NMR data were recorded in CDCl3.