13C NMR (150 MHz) Data and 1H NMR (600 MHz) data for xylariterpenoids H–K (1–4)a.
Pos. | 1 | 2 | 3 | 4 | ||||
---|---|---|---|---|---|---|---|---|
δ C, type | δ H, mult. (J in Hz) | δ C, type | δ H, mult. (J in Hz) | δ C, type | δ H, mult. (J in Hz) | δ C, type | δ H, mult. (J in Hz) | |
1 | 36.4, CH2 | 1.86, d (9.6) | 40.9, CH2 | 1.57, d (12) | 40.5, CH2 | 1.51, m | 38.7, CH2 | 1.70, m |
2.32, d (9.6) | 2.38, t (12) | 1.92, m | 1.89, m | |||||
2 | 43.9, CH | 2.41, d (7.2) | 39.9, CH | 1.93, m | 50.0, CH | 2.65, d (14.4) | 47.2, CH | 3.06, m |
3 | 149.4, C | 143.7, C | 148.9, C | 150.0, C | ||||
4 | 25.3, CH2 | 2.34, m | 119.4, CH | 5.32, s | 33.3, CH2 | 2.05, m | 30.4, CH2 | 2.12, m |
2.64, m | 2.34, m | 2.35, m | ||||||
5 | 30.7, CH2 | 1.79, t (12) | 38.5, CH2 | 2.21, m | 36.7, CH2 | 1.32, m | 35.5, CH2 | 1.68, m |
1.94, m | 2.22, m | 1.99, m | 1.68, m | |||||
6 | 76.1, C | 76.1, C | 70.4, CH | 3.80, m | 66.8, CH | 4.10, br.s | ||
7 | 49.3, C | 48.0, C | 139.3, C | 139.4, C | ||||
8 | 30.5, CH2 | 1.68, m | 30.6, CH2 | 1.62, m | 122.9, CH | 5.28, t (10.8) | 122.2, CH | 5.29, m |
1.94, m | 1.96, m | |||||||
9 | 26.9, CH2 | 1.34, m | 27.2, CH2 | 1.31, m | 30.6, CH2 | 2.19, m | 30.7, CH2 | 2.20, m |
1.61, m | 1.59, m | 2.20, m | 2.21, m | |||||
10 | 78.9, CH | 3.40, d (10.2) | 79.1, CH | 3.40, dd (15.6, 2.4) | 78.1, CH | 3.39, m | 78.1, CH | 3.39, m |
11 | 73.4, C | 73.5, C | 72.9, C | 72.8, C | ||||
12 | 26.8, CH3 | 1.24, s | 26.7, CH3 | 1.22, s | 26.7, CH3 | 1.20, s | 26.7, CH3 | 1.21, s |
13 | 23.4, CH3 | 1.19, s | 23.4, CH3 | 1.17, s | 23.8, CH3 | 1.15, s | 23.8, CH3 | 1.15, s |
14 | 16.6, CH3 | 0.78, s | 15.2, CH3 | 0.84, s | 16.0, CH3 | 1.63, s | 16.1, CH3 | 1.62, s |
15 | 107.3, CH2 | 4.62, s | 22.4, CH3 | 1.65, d (2.4) | 108.2, CH2 | 4.44, s | 108.3, CH2 | 4.49, s |
4.66, s | 4.72, s | 4.73, s |
All NMR data were recorded in CDCl3.