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. 2019 Jan 9;9(2):1036–1046. doi: 10.1039/c8ra08200f

Hydrogen storage properties of ball milled MgH2 powders doped with abrasive powders of selected metal oxides, carbides and intermetallic compounds.

Catalyst Hydrogenation/dehydrogenation properties Ref.
10 wt% MG-Ti2Ni Absorption/5.7 wt% H2/10 bar/225 °C/400 s, desorption/5.7 wt% H2/200 mbar/225 °C/400 s, cycle-life-time: 30 h (84 cycles) Present work
5 wt% Nb2O5 Absorption/5.2 wt% H2/10 bar/300 °C/400 s,dDesorption/6 wt% H2/0.1 kPa/300 °C/400 s 32
10 wt% Nb2O5 Absorption/5.8 wt% H2/5 bar/300 °C/30 min, desorption/5.8 wt% H2/0.1 bar/300 °C/350 min 33
10 wt% Nb2O5 Absorption/5.0 wt% H2/10 bar/225 °C/1200 s, desorption/5.0 wt% H2/0.02 bar/225 °C/700 s 34
10 wt% Al2O3 Absorption/4.09 wt% H2/15 bar/300 °C/110 min, desorption/NA 35
10 wt% Al2O3 Absorption/4.22 wt% H2/12 bar/320 °C/10 min/max storage capacity: 5.2 wt%, desorption/NA 36
15 wt% VNbO5 Absorption/5.5 wt% H2/20 bar/160 °C/10 min, absorption/desorption 50 cycles/275 °C 37
10 wt% SiC Absorption/3.7 wt% H2/10 bar/350 °C/140 s, desorption/2.5 wt% H2/0.02 bar/350 °C/2000 s 38
10 wt% V0.75Ti0.05Cr0.20 Absorption/3 wt% H2/1 bar/25 °C/75 min/max storage capacity: 6.1 wt%, desorption/5.5 wt% H2/0.01 bar/240 °C/5 min 39
14 wt% TiAl Absorption/4 wt% H2/1 bar/25 °C/100 min/max storage capacity: 5 wt%, desorption/4 wt% H2/0.1 bar/240 °C/7 min 40
7 wt% Mn3.6Ti2.4 Absorption/5.3 wt% H2/10 bar/275 °C/2 min, desorption/5.3 wt% H2/0.02 bar/275 °C/8 min, cycle-life-time: 1400 h (1000 cycles) 41
10 wt% ZrNi5 Absorption/5.3 wt% H2/10 bar/275 °C/1 min, desorption/5.3 wt% H2/0.02 bar/275 °C/12 min, cycle-life-time: 568 h (600 cycles) 42
10 wt% big-cube Zr2Ni Absorption/5.1 wt% H2/10 bar/250 °C/100 s, desorption/5.1 wt% H2/0.02 bar/250 °C/613 s, cycle-life-time: 1250 h (2546 cycles) 43