Selected bond distances (Å) and angles (°) for series of ruthenium chloro complexes.
| p-1Cl | p-2Cl | p-3Cl | p-4Cl | |
|---|---|---|---|---|
| Ru1–Cl1 | 2.464(2) | 2.4058(15) | 2.4462(9) | 2.446(2) |
| Ru1–N1 | 2.087(8) | 2.090(5) | 2.092(3) | 2.057(7) |
| Ru1–N2 | 1.961(4) | 1.946(4) | 1.955(3) | 1.950(7) |
| Ru1–N3 | 2.085(8) | 2.063(4) | 2.075(3) | 2.072(7) |
| Ru1–N4 | 2.025(5) | 2.076(4) | 2.020(3) | 2.031(7) |
| Ru1–N5 | 2.138(4) | 2.099(5) | 2.115(3) | 2.148(6) |
| Cl1–Ru1–N1 | 86.16(13) | 86.18(12) | 84.93(8) | 91.00(19) |
| Cl1–Ru1–N2 | 82.39(14) | 83.36(13) | 86.14(8) | 80.33(19) |
| Cl1–Ru1–N3 | 92.01(15) | 90.47(12) | 96.03(8) | 87.31(19) |
| Cl1–Ru1–N4 | 171.94(13) | 170.54(13) | 169.14(8) | 176.08(18) |
| Cl1–Ru1–N5 | 105.20(12) | 98.03(13) | 101.12(8) | 105.82(19) |
| N1–Ru1–N2 | 79.68(18) | 79.8(2) | 79.50(11) | 80.0(3) |
| N1–Ru1–N3 | 160.20(17) | 159.7(2) | 159.02(11) | 160.3(3) |
| N1–Ru1–N4 | 85.95(18) | 86.08(17) | 84.65(11) | 87.6(3) |
| N1–Ru1–N5 | 101.48(17) | 96.50(19) | 99.99(11) | 95.5(2) |
| N2–Ru1–N3 | 80.53(18) | 79.94(19) | 79.66(11) | 80.4(3) |
| N2–Ru1–N4 | 94.51(19) | 100.58(18) | 94.96(11) | 95.8(3) |
| N2–Ru1–N5 | 172.36(18) | 175.98(18) | 172.67(11) | 172.5(3) |
| N3–Ru1–N4 | 94.83(19) | 98.66(17) | 94.80(11) | 92.7(3) |
| N3–Ru1–N5 | 98.03(17) | 103.79(18) | 100.37(11) | 103.9(3) |
| N4–Ru1–N5 | 78.09(18) | 77.48(18) | 77.71(11) | 78.0(2) |