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. 2019 Jan 22;9(6):3128–3139. doi: 10.1039/c8ra08770a

Activation energy and pre-finger factor of TSPLA obtained by Coats–Redfern method.

β 1 = 10 K min−1 β 2 = 20 K min−1 β 3 = 30 K min−1 β 4 = 40 K min−1
g(α) E 1 (kJ mol−1) ln A1 (s−1) E 2 (kJ mol−1) ln A2 (s−1) E 3 (kJ mol−1) ln A3 (s−1) E 4 (kJ mol−1) ln A4 (s−1)
S1 3.93 −10.75 5.24 −9.61 6.40 −8.84 6.32 −8.59
S2 8.73 −9.09 10.64 −7.95 12.14 −7.20 12.14 −6.93
S3 18.33 −6.62 21.45 −5.37 23.78 −4.52 23.78 −0.50
S4 27.94 −4.47 32.18 −3.08 35.33 −2.12 35.42 −1.92
S5 47.14 −0.48 53.63 1.20 58.53 2.40 58.70 2.56
S6 31.09 −4.32 35.58 −2.91 38.91 −1.92 39.24 −1.70
S7 38.24 −2.57 43.73 −1.03 47.72 0.053 47.97 0.25
S8 41.08 −1.91 46.89 −0.32 51.12 0.79 51.38 0.98
S9 72.66 3.48 82.06 5.54 88.88 7.03 89.62 7.21
S10 81.39 4.52 91.95 6.70 99.52 8.61 100.27 8.75
S11 85.05 4.52 96.11 6.79 104.01 8.45 104.76 8.58
S12 1.83 −11.99 4.36 −10.01 1.50 −11.28 4.49 −9.35
S13 6.90 −9.75 8.73 −8.58 10.23 −7.80 9.56 −7.76
S14 10.31 −8.90 12.39 −7.77 13.97 −7.01 14.05 −6.76
S15 38.33 −3.26 43.73 −1.72 47.72 −0.64 48.05 −0.44
S16 41.07 −3.01 46.89 −1.42 51.13 −0.30 51.38 −0.12
S17 17.21 −7.23 20.12 −6.01 22.28 −5.19 22.45 −4.95
S18 92.62 5.80 104.51 8.20 113.24 9.96 113.82 10.06