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. 2019 Jan 22;9(6):3128–3139. doi: 10.1039/c8ra08770a

Activation energy and pre-finger factor of TSPLA–5%DOPO obtained by Coats–Redfern method.

β 1 = 10 K min−1 β 2 = 20 K min−1 β 3 = 30 K min−1 β 4 = 40 K min−1
g(α) E 1 (kJ mol−1) ln(A1) (s−1) E 2 (kJ mol−1) ln(A2) (s−1) E 3 (kJ mol−1) ln(A3) (s−1) E 4 (kJ mol−1) ln(A4) (s−1)
S1 3.83 1.88 22.45 5.09 2.83 3.91 7.99 4.52
S2 5.94 3.78 6.65 4.57 7.48 5.70 8.31 6.34
S3 14.13 6.09 14.97 6.88 16.63 7.99 16.63 8.63
S4 22.45 8.00 24.11 8.86 25.77 10.03 26.60 10.75
S5 39.08 11.50 41.57 12.41 44.06 13.70 44.90 14.35
S6 25.77 8.13 26.60 9.06 29.10 10.25 29.93 10.85
S7 31.59 9.66 33.26 10.58 35.75 11.90 36.58 12.45
S8 34.09 10.20 35.75 11.15 38.24 12.40 39.08 13.05
S9 61.52 14.80 64.85 15.85 69.01 17.70 70.67 18.05
S10 68.17 15.80 72.33 16.96 77.32 18.50 78.98 18.15
S11 71.50 15.50 75.66 16.60 80.65 18.20 82.31 18.95
S12 1.16 1.24 1.66 2.29 1.00 2.46 8.83 3.74
S13 3.33 2.59 1.83 2.38 4.41 4.47 9.99 5.23
S14 9.98 4.78 10.81 5.56 9.15 5.90 9.39 6.56
S15 31.59 8.94 33.26 9.88 35.75 11.20 36.58 11.85
S16 34.09 9.11 35.75 10.05 38.24 11.30 39.08 11.95
S17 13.30 5.57 24.11 5.76 15.80 7.54 16.63 8.13
S18 80.15 16.5 82.31 17.59 88.13 18.40 91.45 20.05