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. 2019 Jan 23;9(6):2948–2966. doi: 10.1039/c8ra09486a

Optical and thermal properties and device performances of Cz-DPVI, Cz-DMPVI, Cz-DEPVI and TPA-DEPVI.

Emitters Cz-DPVI Cz-DMPVI Cz-DEPVI TPA-DEPVI
λ ab (nm) (sol/film) 252, 320, 356/323, 360 254, 328, 360/330, 364 260, 331, 366/334, 372 255, 332, 368/335, 370
λ em (nm) (sol/film) 390, 408/412, 420 399, 415/420, 432 401, 428/410, 440 409, 432/415, 449
T g/Td5 (°C) 163/521 174/546 195/566 190/558
ϕ (soln/film) 0.76/0.83 0.80/0.89 0.82/0.91 0.78/0.86
HOMO/LUMO (eV) −5.60/−2.58 −5.59/−2.61 −5.46/−2.70 −5.50/−2.65
E g (eV) 3.02 2.93 2.76 2.85
E S/ET (eV) 2.62/2.34 2.74/2.40 2.88/2.49 2.80/2.46
τ (ns) 1.83 1.92 2.32 2.10
k r × 108 (s−1) 4.15 4.17 3.53 3.71
k nr × 108 (s−1) 1.31 1.03 0.78 1.05
V 1000 (V) 3.4 3.2 2.8 2.9
L (cd m−2) 13 629 13 841 13 955 13 856
η ex (%) 4.6 4.9 6.9 5.7
η c (cd A−1) 4.9 5.4 6.0 5.7
η p (lm W−1) 4.3 5.0 5.4 5.2
CIE (x, y) 0.15, 0.08 0.15, 0.08 0.15, 0.06 0.15, 0.07
EL (nm) 419 430 439 442
η IOE (%)a 22.0 23.0 24.5 23.5
η S 26.5 25.8 26.9 27.3