Comparison of present methodology with reported catalysts.
| Entry | Catalyst | Solvent | Conditions | Time (h/min) | Yield (%) | eec | Reference |
|---|---|---|---|---|---|---|---|
| 1 | HCl/chloro sulphonic acid | MeOH | 60 °C | 8.0 h | 96 | — | 37 |
| 2 | HCl | EtOH | Reflux/MWa | 12 h | 94 | — | 38 |
| 3 | HCl | MeOH | Reflux | Overnight | 59 | — | 39 |
| 4 | Chloro sulphonic acid | — | 60 °C/USb | 30 min | 92 | — | 40 |
| 5 | HCl | EtOH | Reflux | 12 h | 74 | — | 41 |
| 6 | HCl/silica gel/acidic alumina/montmorillonite-K10 clay | MeOH | 110 °C/MWa | 4–6 min | 60/83/90/85 | — | 42 |
| 7 | K2CO3 | EtOH/H2O | Reflux/MWa | 7 h | 53 | — | 43 |
| 8 | VCl3 | Acetonitrile | Reflux | 2 h | 82 | — | 44 |
| 9 | l-Proline | Water | MWa | 10 min | 90 | 98 | Present work |
Microwave conditions.
Ultrasonication.
ee = enantiomeric excess.