NMR data of compound 1a.
Position | 1a | 1b | ||
---|---|---|---|---|
δ C, type | δ H (J in Hz) | δ C, type | δ H (J in Hz) | |
1/1′ | 179.5, C | 179.5, C | ||
2/2′ | 159.0, C | 159.0, C | ||
3/3′ | 121.2, C | 121.2, C | ||
4/4′ | 188.3, C | 188.3, C | ||
5/5′ | 145.4, C | 145.4, C | ||
6/6′ | 139.8, C | 139.8, C | ||
7/7′ | 152.8, C | 152.8, C | ||
8/8′ | 102.5, CH | 7.17, s | 102.5, CH | 7.17, s |
9/9′ | 127.2, C | 127.2, C | ||
10/10′ | 112.5, C | 112.5, C | ||
11 | 120.4, C | 120.4, C | ||
12 | 43.5, CH2 | 3.03, s | 43.5, CH2 | 3.03, s |
13 | 169.9, C | 169.9, C | ||
14 | 24.8, CH3 | 1.88, s | 24.8, CH3 | 1.88, s |
15 | 61.6, CH3 | 4.10, s | 61.6, CH3 | 4.09, s |
11′ | 120.1, C | 120.1, C | ||
12′ | 43.3, CH2 | 3.08, s | 43.3, CH2 | 3.08, s |
13′ | 168.5, C | 168.5, C | ||
14′ | 25.1, CH3 | 1.86, s | 25.1, CH3 | 1.86, s |
15′ | 61.6, CH3 | 4.09, s | 61.6, CH3 | 4.09, s |
16′ | 52.5, CH3 | 3.68, s | 52.5, CH3 | 3.68, s |
Measured in CDCl3–CD3OD (2 : 1) (1H at 600 MHz and 13C at 150 MHz).