NMR data of compound 2a.
Position | 2a | 2b | ||
---|---|---|---|---|
δ C,b type | δ H (J in Hz) | δ C,b type | δ H (J in Hz) | |
1/1′ | 179.1, C | 179.1, C | ||
2/2′ | 158.6, C | 158.6, C | ||
3/3′ | n.d.c | n.d.c | ||
4/4′ | 188.3, C | 188.3, C | ||
5/5′ | 145.5, C | 145.5, C | ||
6/6′ | 139.1, C | 139.1, C | ||
7/7′ | 152.1, C | 152.1, C | ||
8/8′ | 102.0, CH | 7.21, s | 102.0, CH | 7.20, s |
9/9′ | 127.1, C | 127.1, C | ||
10/10′ | 112.2, C | 112.2, C | ||
11/11′ | 119.2, C | 119.2, C | ||
12/12′ | 42.9, CH2 | 3.12, s | 42.9, CH2 | 3.10, s |
13/13′ | 171.4, C | 171.4, C | ||
14/14′ | 24.6, CH3 | 1.91, s | 24.6, CH3 | 1.88, s |
15/15′ | 61.2, CH3 | 4.13, s | 61.2, CH3 | 4.12, s |
OH-5/OH-5′ | 12.06, s | 12.06, s |
Measured in CDCl3 (1H at 600 MHz and 13C at 150 MHz).
Data were extracted from the HSQC and HMBC spectra.
n.d. = not detected.