¹H and ¹³C NMR chemical shifts of CMSPA90-1 (ppm).

Sugar residue	Chemical shifts
	C1/H1	C2/H2	C3/H3	C4/H4	C5/H5	C6/H6
A: β-d-Gal(1→	107.48/5.00	76.71/3.94	80.73/4.17	81.12/4.05	76.53/3.94	66.13/3.72
B: →5)-α-l-Ara(1→	106.88/5.07	83.90/3.88	76.76/4.09	84.10/3.63	76.37/4.07
C: →3)-α-l-Ara(1→	106.88/5.07	81.41/4.04	83.98/4.22	79.90/4.18	65.99/3.72
D: →3,6)-α-d-Man(1→	106.38/5.16	84.44/3.88	81.29/4.17	84.90/3.98	76.44/3.94	66.40/4.04
E: →6)-α-d-Glc(1→	95.46/5.12	72.19/3.64	76.37/3.88	79.93/4.05	79.57/4.17	65.99/3.86