Influences of reaction temperature and time on 1-dodecene hydroformylation^a.

Entry	T (°C)	t (h)	Conv.b (%)	Ald.c (%)	Ace.d (%)	L/Be	TOFf (h−1)
1	60.0	1.0	12.3	88.4	2.2	1.9	410
2	70.0	1.0	28.8	94.5	2.0	2.5	960
3	80.0	0.25	40.2	97.5	0.0	2.7	5359
4	80.0	0.5	61.0	94.5	2.2	2.4	4066
5	80.0	0.75	77.4	91.5	5.4	2.5	3440
6	80.0	1.0	99.7	92.7	6.5	2.5	3323
7	80.0	2.0	99.8	74.1	23.4	2.1	1663
8	80.0	4.0	99.7	43.7	53.8	1.6	831
9	90.0	1.0	99.7	65.9	30.4	2.0	3323
10	100.0	1.0	99.6	36.5	58.0	1.3	3320
11g	100.0	1.0	99.6	94.5	0.0	2.5	3320

^aReaction conditions: Rh = 1.35 × 10⁻³ mmol, [P]/[Rh] = 20.0, S/C = 3333, 1-dodecene = 1.0 mL, methanol = 10.0 mL, P = 2.0 MPa (CO : H₂ = 1.0 : 1.0).

^bSee Table 1.

^cSee Table 1.

^dSee Table 1.

^eSee Table 1.

^fSee Table 1.

^g30 μL of triethylamine was added.