Hydroformylation of other long chain alkenes^a.

Entry	Alkene	Conv.b (%)	Ald.c (%)	Ace.d (%)	L/Be	TOFf (h−1)
1	1-Hexene	97.8	90.6	7.0	2.3	3260
2	1-Octene	98.0	93.8	5.2	2.5	3267
3	1-Decene	99.0	95.1	3.9	2.4	3300
4	1-Dodecene	99.7	92.7	6.5	2.5	3323
5g	Cyclohexene	93.5	92.3	0.0	—	390
6h	Norbornene	92.5	94.6	0.0	—	385
7i	Dicyclopentadiene	93.0	95.5	0.0	—	388

^aReaction conditions: Rh = 1.35 × 10⁻³ mmol, [P]/[Rh] = 20.0, S/C = 3333, P = 2.0 MPa (CO : H₂ = 1.0 : 1.0), T = 80.0 °C, t = 1.0 h.

^bSee Table 1.

^cSee Table 1.

^dSee Table 1.

^eSee Table 1.

^fSee Table 1.

^gRh = 2.70 × 10⁻³ mmol, [P]/[Rh] = 20.0, S/C = 1667, P = 2.0 MPa (CO : H₂ = 1.0 : 1.0), T = 120.0 °C, t = 4.0 h.

^hRh = 2.70 × 10⁻³ mmol, [P]/[Rh] = 20.0, S/C = 1667, P = 2.0 MPa (CO : H₂ = 1.0 :1 .0), T = 120.0 °C, t = 4.0 h.

ⁱRh = 2.70 × 10⁻³ mmol, [P]/[Rh] = 20.0, S/C = 1667, P = 2.0 MPa (CO : H₂ = 1.0 : 1.0), T = 120.0 °C, t = 4.0 h.