The parameters for the kinetic models of TC and LEV adsorbed to modified biochars.
Model | Parameters | IP–LEV | IP–TC | PI–LEV | PI–TC |
---|---|---|---|---|---|
Pseudo-first-order | q e (mmol g−1) | 0.0964 | 0.1572 | 0.5451 | 0.2494 |
k 1 (h−1) | 0.2081 | 0.1613 | 5.576 | 2.822 | |
R 2 | 0.8991 | 0.9865 | 0.9492 | 0.9050 | |
Pseudo-second-order | q e (mmol g−1) | 0.1119 | 0.1948 | 0.5686 | 0.2620 |
k 2 (g (mmol h)−1) | 2.439 | 0.870 | 15.878 | 15.50 | |
R 2 | 0.90417 | 0.9909 | 0.9577 | 0.9175 | |
Intra-particle diffusion | k i (mmol h0.5 g−1) | 0.01957 | 0.03382 | 0.04312 | 0.02992 |
C | 0.01230 | 7.102 × 10−4 | 0.4010 | 0.1405 | |
R 2 | 0.9871 | 0.9926 | 0.5687 | 0.8254 |