Substrate scope catalyzed by Fe3O4@SiO2-APTES-MnLGDC.
| |||||||
|---|---|---|---|---|---|---|---|
| Entry | Substrate | Major product | Time (h) | Conv.c (%) | Selectivityd (%) | TONe | |
| Major product | Other product | ||||||
| 1 |
|
|
91 | 9 | 92 | ||
| 2 |
|
|
10 | 96 | 98 | 2 | 95 |
| 3 |
|
|
10 | 64 | 48 | 52 | 47 |
| 4 |
|
|
10 | 93 | 100 | — | 93 |
| 5a |
|
|
10 | 91 | 91 | 9 | 89 |
| 6 |
|
|
10 | 80 | 100 | — | 80 |
| 7b |
|
|
10 | 57 | 100 | — | 86 |
| 8b |
|
20 | 71 | 100 | — | 107 | |
| 9b |
|
|
20 | 87 | 92 | 8 | 131 |
TBHP (2 eq., 70%).
TBHP (4 eq., 70%).
Conversions were determined by GC.
Selectivity to product = [product%/(products%)] × 100.
TON = (substrate/catalyst) × conversion.