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. 2019 May 7;9(25):14343–14351. doi: 10.1039/c9ra02284h

Substrate scope catalyzed by Fe3O4@SiO2-APTES-MnLGDC.

graphic file with name c9ra02284h-u2.jpg
Entry Substrate Major product Time (h) Conv.c (%) Selectivityd (%) TONe
Major product Other product
1 graphic file with name c9ra02284h-u3.jpg graphic file with name c9ra02284h-u4.jpg 91 9 92
2 graphic file with name c9ra02284h-u5.jpg graphic file with name c9ra02284h-u6.jpg 10 96 98 2 95
3 graphic file with name c9ra02284h-u7.jpg graphic file with name c9ra02284h-u8.jpg 10 64 48 52 47
4 graphic file with name c9ra02284h-u9.jpg graphic file with name c9ra02284h-u10.jpg 10 93 100 93
5a graphic file with name c9ra02284h-u11.jpg graphic file with name c9ra02284h-u12.jpg 10 91 91 9 89
6 graphic file with name c9ra02284h-u13.jpg graphic file with name c9ra02284h-u14.jpg 10 80 100 80
7b graphic file with name c9ra02284h-u15.jpg graphic file with name c9ra02284h-u16.jpg 10 57 100 86
8b graphic file with name c9ra02284h-u17.jpg 20 71 100 107
9b graphic file with name c9ra02284h-u18.jpg graphic file with name c9ra02284h-u19.jpg 20 87 92 8 131
a

TBHP (2 eq., 70%).

b

TBHP (4 eq., 70%).

c

Conversions were determined by GC.

d

Selectivity to product = [product%/(products%)] × 100.

e

TON = (substrate/catalyst) × conversion.