Summary of the optical and the electrochemical data of compounds TPA-PTZ-BDP, PTZ-TPA-BDP and N-PTZ-BDP.
Dye | λ a (nm) | λ max b (nm) | ε max | λ onset (nm) | E opt (eV) | E 1/2ox (V) | E 1/2red (V) | IP (eV) | EA (eV) | E fund (eV) |
---|---|---|---|---|---|---|---|---|---|---|
TPA-PTZ-BDP | 335 | 711 | 4.4 × 104 | 754 | 1.64 | 0.23 | −1.40 | −5.03 | −3.40 | 1.63 |
686 | ||||||||||
PTZ-TPA-BDP | 355 | 717 | 6.2 × 104 | 777 | 1.59 | 0.20 | −1.38 | −5.00 | −3.42 | 1.58 |
697 | ||||||||||
N-PTZ-BDP | 334 | 721 | 6.3 × 104 | 786 | 1.57 | 0.26 | −1.30 | −5.06 | −3.50 | 1.56 |
702 |
Measured in DCM solution.
Measured in thin film.