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. 2019 May 28;9(29):16496–16508. doi: 10.1039/c9ra02757b

The kinetic parameters for different operating conditions.

Parameters k/min-1 R 2
pH Other conditions: catalyst = 200 mg L−1, PMS = 2 mM, DCF = 30 mg L−1
2 0.005 0.923
3 0.007 0.949
4 0.008 0.929
5 0.015 0.969
6 0.017 0.904
7 0.022 0.920
8 0.015 0.914
9 0.009 0.919
10 0.005 0.938
Catalyst dosage (mg L−1) Other conditions: pH = 7, PMS = 2 mM, DCF = 30 mg L−1
25 0.010 0.960
100 0.015 0.977
250 0.019 0.969
500 0.024 0.922
750 0.024 0.919
1000 0.015 0.966
PMS dosage (mg L−1) Other conditions: pH = 7, catalyst = 500 mg L−1, DCF = 30 mg L−1
0.25 0.009 0.989
0.5 0.011 0.983
1 0.015 0.960
2 0.021 0.922
4 0.032 0.926
6 0.018 0.891
8 0.017 0.986
DCF concentration (mg L−1) Other conditions: pH = 7, catalyst = 500 mg L−1, PMS = 4 mM
10 0.038 0.968
20 0.032 0.923
30 0.032 0.926
50 0.012 0.983
Temperature (°C) Other conditions: pH = 7, catalyst = 500 mg L−1, PMS = 4 mM, DCF = 30 mg L−1
10 0.016 0.985
20 0.018 0.954
25 0.022 0.932
30 0.032 0.926