Calculated reaction energies, E_r, and barriers, E_a, (both in meV) of polaron migrations in all considered paths of the Li-intercalated V₂O₅ system using LE and NEB methods.

Path	E r	E a
		LE	NEB
Path-a
1 → 2a	1	135	4
2a → 3a	188	302	195
3a → 4a	−1	132	122
4a → 1	−180	119	15
Path-b1
1 → 2by	120	235	205
2by → 3by	10	228	218
3by → 1	−130	121	109
Path-b2
1 → 2bx	188	302	196
2bx → 2by	−67	148	21
2by → 3bx	40	180	88
3bx → 3by	−30	162	29
3by → 4bx	33	193	75
4bx → 1	−164	123	21
Path-c
1 → 2c	7	284	166
2c → 3c	146	302	179
3c → 1	−153	161	25