Parameters for pseudo-first order, pseudo-second order and Elovich kinetic models, and intra-particles diffusion model for MB and CV adsorption.
| Parameter | Adsorbing dye | ||
|---|---|---|---|
| MB | CV | ||
| Pseudo-first order | q e(cal) | 49.0 | 48.0 |
| k 1 | 5.08 | 2.60 | |
| R 2 | 0.8664 | 0.8912 | |
| Pseudo-second order | q e(cal) | 49.9 | 49.2 |
| k 2 | 0.23 | 0.11 | |
| R 2 | 0.9896 | 0.9666 | |
| Elovich | α(×109) | 6.63 | 0.03 |
| β | 0.50 | 0.40 | |
| R 2 | 0.6997 | 0.7716 | |
| Intra-particle diffusion | |||
| Stage 1 | k d1 | 48.2 | 44.5 |
| C 1 | 4.95 | 0.93 | |
| R 2 | 0.8491 | 0.9698 | |
| Stage 2 | k d2 | 1.60 | 2.37 |
| C 2 | 45.5 | 41.1 | |
| R 2 | 0.9528 | 0.9661 | |
| Stage 3 | k d3 | 0.028 | 0.032 |
| C 3 | 49.5 | 49.0 | |
| R 2 | 0.5653 | 0.7519 | |