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. 2019 Jul 8;9(37):21278–21287. doi: 10.1039/c9ra02928a

Retention time (Rt), wavelengths of maximum absorption (λmax), mass spectral data, and tentative identification of phenolic compounds detected in W. filifera seeds.

Peak R t (min) λ max (nm) Pseudomolecular ion [m – H] (m/z) MS2 (m/z) Tentative identification
1 12.0 260, 293 331 Galloylglucose
2 16.3 280, 307 451 (epi)Catechin glucoside
3 20.2 279 577 451, 425, 407, 289 B-type procyanidin dimer (B3)
4 20.7 279 577 B-type procyanidin dimer (B1)
5 21.1 278 865 695, 577, 425, 407, 287 B-type procyanidin trimer (C2)
6 22.5 577 B-type procyanidin dimer (B4)
7 22.9 577 B-type procyanidin dimer (B2)
8 23.7 863 A-type procyanidin trimer
9 25.4 1153 849, 577, 407, 287 B-type procyanidin tetramer
10 27.5 278 289 245, 203, 179, 109 Epicatechin
11 28.4 561 435, 407, 289 (epi)Catechin–(epi)afzelechin dimer
12 29.4 283 449 287, 269 Dihydrokaempferol hexoside
13 30.9 863 711, 575, 423 A-type procyanidin trimer
14 32.6 865 B-type procyanidin trimer
15 34.1 865 B-type procyanidin trimer
16 38.3 865 B-type procyanidin trimer
17 39.1 1153 B-type procyanidin tetramer
18 40.5 865 B-type procyanidin trimer
19 41.4 849 697, 577, 407, 287 B-type proanthocyanidin trimer containing one afzelechin unit
20 43.3 254, 353 689 301 Quercetin rutinoside sulfate
21 43.8 1441 B-type procyanidin pentamer
22 45.3 256, 358 703 315 Isorhamnetin rutinoside sulfate
23 45.3 577 B-type procyanidin dimer
24 46.5 849 B-type procyanidin trimer containing one afzelechin unit
26 50.4 557 315 Isorhamnetin glucoside sulfate
28 61.8 255, 353 463 301 Quercetin glucoside
29 65.1 577 B-type procyanidin dimer
30 865 B-type procyanidin trimer