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. 2022 Apr 16;61(17):6624–6640. doi: 10.1021/acs.inorgchem.2c00526

Table 5. Optimal Isomerization Reaction Conditions for the Studied Systems in the Solid State Based On the IR Spectroscopy Resultsa.

compound λirr (nm) Tirr (K) Trev (K)
Ni-2a 470–530 10–140 220
Ni-2b 530 180 220
Cu-2a 590 10 60
Cu-2b 405 10 80
a

Symbols are defined as follows: λirr, the most efficient LED central wavelength regarding the generation of the metastable linkage isomer; Tirr, the temperature at which the metastable linkage isomer’s population is the highest; and Trev, the temperature at which the system reverts back to the ground state.