Skip to main content
. 2019 Aug 1;9(41):23876–23887. doi: 10.1039/c9ra04096j

The oxidative cyclization between acetophenone oxime acetate and phenylacetic acid utilizing different catalystsa.

graphic file with name c9ra04096j-u2.jpg
Entry Homogeneous catalyst Heterogeneous catalyst Yieldb (%)
1 FeCl3 26
2 FeCl2 6
3 Fe(NO3)3 3
4 FeSO4 13
5 CuSO4 57
6 Cu(NO3)2 8
7 NiSO4 38
8 Co(NO3)2 4
9 La(NO3)2 2
10 Sr(NO3)2 39
11 Cu(BDC) 70
12 ZIF-8A 60
13 UiO-66·TFA 43
14 La2O3 19
15 CoO 11
16 SrO 38
17 LaCoCo3 40
18 La0.6Sr0.4CoO3 83
a

Reaction conditions: acetophenone oxime acetate (0.6 mmol), phenylacetic acid (0.2 mmol), DTBP (0.6 mmol), toluene (2 mL), catalyst (5 mol%), 140 °C, under air for 2 h and under argon for 6 h.

b

GC yield.