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. 2022 Apr 18;55(9):1324–1336. doi: 10.1021/acs.accounts.2c00113

Figure 7.

Figure 7

(A) Analysis of the productive fractionation, f, of TMSCF3 into desired (Ar-TMS, 23) and undesired (TMSF) products during silylation of 18. The fractionation increases as the reactions proceed and as the initial ratio [18]0/[TMSCF3]0 is raised. (B) Insight from the changes in f, informing the slow addition of TMSCF3. Data from ref (45).