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(A) Partitioning analysis by competition of alkene 19 with aldehyde 28 during NaI-mediated difluorocyclopropanation. (B) Chain reaction identified for CF2-generation from TMSCF3. (C) NaI-mediated decomposition of TMSCF3 in the absence of alkene 19, and identification of species arising from chain-branching autoacceleration. Data from ref (4).
