Retention times (min), milligrams of injected VOC, milligrams of VOC in the back tube.
VOC | RT (min) | Injected VOC (mg) | VOC in back tubea (mg) |
---|---|---|---|
4@1 | 13.7 | 1.226 | 0.502 ± 0.025 |
4@2 | 13.7 | 1.226 | 0.441 ± 0.023 |
4@3 | 13.7 | 1.226 | 0.429 ± 0.020 |
5@1 | 17.5 | 1.214 | 0.461 ± 0.023 |
5@2 | 17.5 | 1.214 | 0.387 ± 0.020 |
5@3 | 17.5 | 1.214 | 0.290 ± 0.014 |
6@1 | 20.7 | 1.212 | 0.379 ± 0.019 |
6@2 | 20.7 | 1.212 | 0.315 ± 0.016 |
6@3 | 20.7 | 1.212 | 0.303 ± 0.015 |
7@1 | 23.7 | 1.207 | 0.362 ± 0.018 |
7@2 | 23.7 | 1.207 | 0.265 ± 0.013 |
7@3 | 23.7 | 1.207 | 0.277 ± 0.013 |
8@1 | 26.8 | 0.120 | 0.349 ± 0.017 |
8@2 | 26.8 | 0.120 | 0.241 ± 0.012 |
8@3 | 26.8 | 0.120 | 0.134 ± 0.007 |
9@1 | 9.7 | 0.130 | —b |
9@2 | 9.7 | 0.130 | —b |
9@3 | 9.7 | 0.130 | —b |
10@1 | 12.2 | 0.126 | 0.416 ± 0.021 |
10@2 | 12.2 | 0.126 | 0.391 ± 0.019 |
10@3 | 12.2 | 0.126 | 0.467 ± 0.023 |
11@1 | 15.5 | 0.124 | 0.369 ± 0.018 |
11@2 | 15.5 | 0.124 | 0.311 ± 0.015 |
11@3 | 15.5 | 0.124 | 0.219 ± 0.011 |
12@1 | 18.7 | 0.123 | 0.309 ± 0.015 |
12@2 | 18.7 | 0.123 | 0.235 ± 0.012 |
12@3 | 18.7 | 0.123 | 0.173 ± 0.009 |
Data from three independent experiments.
Calibration plots are not reproducible likely due to the low adsorption of this particular VOC.