Table 3. Data Extracted from TG Measurements.
| sample | 10 min absorption (%) | 10 min release (%) | capacity loss (%/cycle) | release onset (°C) | heat of desorption (J/g) | capacity (mmol/g) | amine efficiencya (CO2/NH2) |
|---|---|---|---|---|---|---|---|
| PAEMA | 0b | 0b | 0b | 59 | 2.0 | 0.07 | 0.01 |
| PAEMA REG | 90.5 | 90.4 | 6.3 | 77 | 110 | 1.8 | 0.29 |
| PGEMA 7 | 92.7 | 87.9 | 2.8 | 72 | 163 | 2.4 | 0.40 |
| PGEMA 19 | 79.7 | 88.8 | 3.2 | 62 | 129 | 2.0 | 0.34 |
| PGEMA 28 | 76.4 | 82.1 | 4.7 | 51 | 79 | 1.3 | 0.22 |
| PEO–PAEMA | 0b | 0b | 0b | 48 | 0b | 0.09 | 0.02 |
| PEO–PAEMA REG | 98.3 | 88.4 | 11.4 | 74 | 55 | 0.6 | 0.10 |
| PEO–PGEMA 11 | 97.8 | 90.1 | 1.5 | 73 | 59 | 1.0 | 0.18 |
| PEO–PGEMA 22 | 76.5 | 67.5 | 3.1 | 53 | 100 | 1.8 | 0.31 |
| PEO–PGEMA 29 | 79.2 | 84.4 | 0b | 46 | 72 | 1.3 | 0.21 |
Calculation based on theoretical 100% NH2 content. The theoretical values agree with actual amine content based on titration (Table S6).
Values are not exactly 0 but are very small and can be considered negligible.