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. 2021 Dec 9;38(17):5197–5208. doi: 10.1021/acs.langmuir.1c02321

Table 3. Data Extracted from TG Measurements.

sample 10 min absorption (%) 10 min release (%) capacity loss (%/cycle) release onset (°C) heat of desorption (J/g) capacity (mmol/g) amine efficiencya (CO2/NH2)
PAEMA 0b 0b 0b 59 2.0 0.07 0.01
PAEMA REG 90.5 90.4 6.3 77 110 1.8 0.29
PGEMA 7 92.7 87.9 2.8 72 163 2.4 0.40
PGEMA 19 79.7 88.8 3.2 62 129 2.0 0.34
PGEMA 28 76.4 82.1 4.7 51 79 1.3 0.22
PEO–PAEMA 0b 0b 0b 48 0b 0.09 0.02
PEO–PAEMA REG 98.3 88.4 11.4 74 55 0.6 0.10
PEO–PGEMA 11 97.8 90.1 1.5 73 59 1.0 0.18
PEO–PGEMA 22 76.5 67.5 3.1 53 100 1.8 0.31
PEO–PGEMA 29 79.2 84.4 0b 46 72 1.3 0.21
a

Calculation based on theoretical 100% NH2 content. The theoretical values agree with actual amine content based on titration (Table S6).

b

Values are not exactly 0 but are very small and can be considered negligible.