Alcohol oxidation study using Na/Ag ionic electrolytea.
| Entry | Alcohol | Aldehyde | Conv. (%) |
|---|---|---|---|
| 1 |
|
|
≥99 |
| 2 |
|
|
59 |
| 3 |
|
|
97 |
| 4 |
|
|
70 |
| 5 |
|
|
66 |
| 6 |
|
|
69 |
| 7 |
|
|
72 |
| 8 |
|
|
70 |
| 9 |
|
|
73 |
| 10 |
|
|
66 |
| 11 |
|
|
75 |
| 12 |
|
|
60 |
| 13 |
|
|
10 |
| 14b |
|
|
88 |
Reaction conditions: 0.2 mmol alcohol, 20 mg dye-ZnO, 1.24 M Na/Ag solution electrolyte, 9.6 × 10−5 mol TEMPO, 0.5 mL H2O, 7 hours. OSRAM® VIALOX 70W incandescent lamp irradiation (65 600 lumens). Aldehyde product conversion was determined by GC-MS.
No dimethylmalonaldehyde was detected.