Correlation coefficient, rate constant and half-life obtained by fitting the release data of hexaconazole and dazomet from CHDEN5 in phosphate buffer solution at pH 5.5 using five different kinetic mathematical models.
Fungicides | Nanoparticle | Correlation coefficient, R2 | Rate constant of pseudo-second order, k (mg h−1) | t 1/2 of pseudo-second order (h) | ||||
---|---|---|---|---|---|---|---|---|
Pseudo-first order | Pseudo-second order | Higuchi model | Hixson–Crowell model | Korsmeyer–Peppas model | ||||
Hexaconazole | CHDEN5 | 0.8095 | 0.9977 | 0.7919 | 0.4395 | 0.8677 | 0.0108 | 53 |
CHDEN20 | 0.6775 | 0.9998 | 0.7919 | 0.3576 | 0.8677 | 0.0108 | 66 | |
Dazomet | CHDEN5 | 0.4697 | 0.9997 | 0.8068 | 0.2787 | 0.8712 | 0.0132 | 15 |
CHDEN20 | 0.2183 | 0.9997 | 0.8068 | 0.1126 | 0.8712 | 0.0132 | 19 |