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. 2019 Sep 4;9(48):27789–27799. doi: 10.1039/c9ra05831a

Photolatency results of Ru dimer/ITX/monomer mixture in CD2Cl2 ([Monomer] = 1 M). All the samples were stored in the dark (Ru dimer/ITX/monomer = 1/2.5/510 equiv.).

Entry Precatalyst Monomer Reaction time (h) Conv.a (%) σ cis a
a Ru-1 NB 4 17.6 30
b Ru-1 ENB 4 0 n.d
c Ru-2 NB 4 <1.0 n.d
d Ru-2 NB 168 1.4 23
e Ru-3 NB 4 90 24
a

Determined by 1H-NMR.