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. 2019 Sep 17;9(50):29347–29356. doi: 10.1039/c9ra05544d

Conversion of glucose using different Keggin-type polyoxometalate catalysts in batch mode at 160 °C. Reaction conditions: 250 mmol L−1 glucose, 1 mmol catalyst, 100 g water as solvent, 160 °C, 60 bar oxygen pressure, 1000 rpm stirrer speed, 24 hours reaction time.

Entry Catalyst FA-yield [%] AA-yield [%] GA-yield [%] CO2-yield [%] CO-yield [%] Total carbon yield [%]
1 HPA-Mo 28.2 6.7 3.2 46.9 4.0 89.0
2 HPA-Ta 30.0 7.0 2.3 51.3 5.1 95.7
3 HPA-Nb 28.5 7.3 3.0 42.6 5.0 86.4