Physical properties of 66BT, 44BT and 44TT.
| Polymer | λ max a (nm) | λ max b (nm) | E opt c (eV) | E HOMO c (eV) | E LUMO d (eV) |
|---|---|---|---|---|---|
| 66BT | 487 | 503 | 2.06 | −5.30 | −3.24 |
| 44BT | 487 | 496 | 2.08 | −5.30 | −3.22 |
| 44TT | 483 | 505 | 2.05 | −5.40 | −3.35 |
| P3HT | 451 | 505 | 1.85 | −5.05 | −3.20 |
| ITIC | 676 | 707 | 1.70 | −5.75 | −4.05 |
Determined using the absorption profiles of solution samples in chloroform.
Determined from the as-cast thin films.
Determined using cyclic voltammetry curves of the thin films.
Determined using a combination of the optical band-gap and the HOMO energy levels obtained from CV measurements of thin film samples.