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. 2019 Sep 25;9(52):30496–30502. doi: 10.1039/c9ra06909g

Physical properties of 66BT, 44BT and 44TT.

Polymer λ max a (nm) λ max b (nm) E opt c (eV) E HOMO c (eV) E LUMO d (eV)
66BT 487 503 2.06 −5.30 −3.24
44BT 487 496 2.08 −5.30 −3.22
44TT 483 505 2.05 −5.40 −3.35
P3HT 451 505 1.85 −5.05 −3.20
ITIC 676 707 1.70 −5.75 −4.05
a

Determined using the absorption profiles of solution samples in chloroform.

b

Determined from the as-cast thin films.

c

Determined using cyclic voltammetry curves of the thin films.

d

Determined using a combination of the optical band-gap and the HOMO energy levels obtained from CV measurements of thin film samples.