Palladium-catalysed aminocarbonylation reactions carried out with aryl iodides 6a–e and morpholine (9). All reactions were carried out at 100 °C for 20 hours in a sealed two-chamber apparatus.

Entry	Aryl iodide	Product	Conversiona (%)	Yieldb (%)
1	6a, R = p-MeO		100 (80)	75 (39)c
2	6b, R = p-NO2		100	88
3	6c, R = p-Br		100	99
4	6d, R = H		100	72
5	6ed		80	75

^aMeasured from ¹H NMR spectra of the crude reaction mixture as compared to the limiting reactant. An example is provided in Fig. SI1 (ESI).

^bIsolated yields after column chromatography.

^cReaction carried out at 80 °C for 20 h.

^d6e = 1-iodonaphthalene.