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. 2019 Oct 2;9(54):31217–31223. doi: 10.1039/c9ra07604b

External functional group test.

graphic file with name c9ra07604b-u18.jpg
Entry Additive Additive conversiona [%] Yielda [%]
1 — — 77
2 PhCN 0 21
3 n-C3H7CN 9 49
4 PhNO2 90 <1
5 EtNO2 87 8
6 PhNH2 77 9
7 n-C6H13NH2 0 80
8 PhCHO 100 16
9 PhCO2Me 0 82
10 n-C3H7CO2Me 4 72
11 PhOH 0 75b
12 n-C5H11OH 6 79b
a

Yields were determined by quantitative GC-FID vs. internal n-pentadecane.

b

2.2 equiv. n-C9H19MgBr.