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Fig. 3. Enthalpy, ΔHSL0i, of Gly–Gly, Gly–Ala, Ala–Gly, Ala–Ala and cyclo(Ala–Gly) in respect to initial sample mass, m0, regardless of the scanning rates. The symbols used were as described in Fig. 2. The dashed line was linear fit through zero origin, where the slope denoted as ΔhSL0i. The scanning rates used were 2000 K s−1 (circles), 4000 K s−1 (up-triangles), 5000 K s−1 (hexagonals), 6000 K s−1 (down-triangles), 8000 K s−1 (diamonds), 10 000 K s−1 (stars). The melting enthalpy for Gly–Gly, Gly–Ala, Ala–Gly, Ala–Ala and cyclo(Ala–Gly) is ΔhSL0Gly–Gly = (40 ± 6) kJ mol−1, ΔhSL0Gly–Ala = (41 ± 5) kJ mol−1, ΔhSL0Ala–Gly = (52 ± 7) kJ mol−1, ΔhSL0Ala–Ala = (45 ± 7) kJ mol−1 and ΔhSL0cyclo(Ala–Gly) = (24 ± 4) kJ mol−1, respectively. The values are already given in the figures, same for Fig. 2.