Influence of the Pd-based compound nature on the conversion of NBD and the selectivity of exo-product formation in the hydrosilylation of NBD by PMDS^a.

Catalyst	Temperature, °C	Conversion, %	Selectivity, %
(AllPdCl)2/R-MOP	30	0	—
	45	10	92
	60	55	86
	75	86	76
Pd(OAc)2/R-MOP	30	0	—
	45	24	87
	60	60	84
	75	70	74

^aNBD/silane molar ratio was 1/1.1; Pd/R-MOP molar ratio was 1/2; Pd-loading was 0.1 mol%; C(NBD) = 2.5 M; the reaction time was 24 h.