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. 2019 Oct 16;9(57):33029–33037. doi: 10.1039/c9ra06784a

Time and temperature dependence of the conversion and selectivity for the hydrosilylation of NBD by PMDS (in the ratio of 1/1.1) in the presence of the (AllPdCl)2/R-MOP catalysta.

Temperature, °C Time, d Conversion, % Selectivity, %
25 1 0
2 0
45 1 10 92
2 37 88
60 1 55 86
2 77 84
75 1 86 76
2 99 76
a

NBD/silane molar ratio was 1/1.1; (AllPdCl)2/R-MOP (1/4 mol. ratio) was the catalyst; Pd-loading was 0.1 mol%; C(NBD) = 2.5 M.