Skip to main content
. 2019 Oct 17;9(57):33403–33412. doi: 10.1039/c9ra07602f

Crystallographic parameters of the cocrystals of phenazine.

Parameters 2(Phen)·12DHB 2(Phen)·13DHB 2.5(Phen)·123THB·2H2O 2.5(Phen)·27DHN
Formula C30H22N4O2 C15H11N2O1 C72H60N10O10 C80H56N10O4
CCDC no. 1946193 1946194 1946196 1946195
Mol. wt 470.51 235.26 1225.30 1221.34
Space group P C2/c P P21/c
a 7.403(3) 14.2921(9) 9.7943(10) 9.382(6)
b 17.584(6) 11.4224(7) 12.0978(12) 18.747(12)
c 18.374(6) 14.4820(10) 13.8839(14) 17.729(11)
α/deg 76.445(11) 90 89.390(3) 90
β/deg 79.816(12) 102.490(6) 78.850(3) 97.799(7)
γ/deg 79.751(12) 90 72.021(3) 90
V3 2265.1(14) 2308.2(3) 1533.1(3) 3089(3)
Density/g cm−3 1.380 1.354 1.327 1.313
Abs. coeff./mm−1 0.089 0.087 0.090 0.083
F(000) 984 984 642 1276
Total no. of reflections 7999 2036 5429 5457
Reflections, I > 2σ(I) 4744 1417 3512 2434
Max. θ/degree 25.047 25.042 25.048 25.048
Ranges (h, k, l) −8 ≤ h ≤ 8 −11 ≤ h ≤ 16 −11 ≤ h ≤ 11 −11 ≤ h ≤ 11
−20 ≤ k ≤ 20 −13 ≤ k ≤ 9 −14 ≤ k ≤ 14 −22 ≤ k ≤ 22
−21 ≤ l ≤ 21 −17 ≤ l ≤ 16 −16 ≤ l ≤ 16 −21 ≤ l ≤ 21
Complete to 2θ (%) 99.9 100.0 99.9 99.6
Data/restraints/parameters 7999/0/653 2036/0/165 5429/2/429 5457/0/426
GooF (F2) 1.126 1.075 1.064 1.073
R indices [I > 2σ(I)] 0.0828 0.0503 0.0631 0.0596
wR2 [I > 2σ(I)] 0.2413 0.1201 0.1966 0.1247
R indices (all data) 0.1310 0.0732 0.0956 0.1491
wR2 (all data) 0.2413 0.1380 0.2352 0.1662