Position | 1a | 2a | 3b | 4a | 5a | 6a | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | |
1 | 173.6 | 173.6 | 172.8 | 172.5 | 172.4 | 172.8 | ||||||
2 | 50.7 | 50.7 | 51.8 | 51.1 | 51.1 | 50.1 | ||||||
3 | 29.0 | 1.76 dd (8.4, 13.9) | 29.0 | 1.76 m | 41.4 | 1.86 d (13.7) | 40.5 | 2.23 dd (7.7, 13.1) | 40.5 | 2.24 dd (5.2, 13.1) | 40.5 | 1.79 d (14.1) |
2.17 t (13.9) | 2.17 t (11.2) | 2.43 dd (8.2, 13.7) | 2.34 dd (7.7, 13.4) | 2.35 dd (7.9, 13.1) | 2.68 dd (8.1, 14.1) | |||||||
4 | 19.7 | 1.97 m | 19.7 | 1.87 m | 71.0 | 4.70 m | 71.2 | 4.73 qd (1.0, 6.0) | 71.3 | 4.75 qd (1.9, 6.7) | 71.5 | 4.78 qd (2.5, 7.7) |
5 | 29.6 | 1.86 t (8.7) | 29.6 | 1.86 m | 41.3 | 2.13 m | 40.7 | 1.90 dd (0.7, 14.4) | 40.7 | 1.91 dd (0.8, 13.5) | 40.9 | 2.04 dd (5.6, 13.3) |
1.98 m | 1.93 m | 2.22 dd (9.1, 14.0) | 2.45 dd (8.4, 14.4) | 2.46 dd (9.0, 13.5) | 2.44 dd (7.7, 13.3) | |||||||
6 | 47.1 | 47.1 | 47.2 | 46.5 | 46.5 | 47.6 | ||||||
7 | 134.4 | 134.3 | 134.3 | 134.1 | 134.1 | 133.7 | ||||||
8 | 144.7 | 144.6 | 145.5 | 144.4 | 144.5 | 144.5 | ||||||
9 | 115.1 | 6.74 s | 115.3 | 6.71 s | 116.4 | 6.94 s | 115.6 | 6.72 s | 115.3 | 6.74 s | 115.3 | 6.74 s |
10 | 122.9 | 120.8 | 124.8 | 120.6 | 123.0 | 123.2 | ||||||
11 | 152.9 | 152.9 | 152.4 | 152.9 | 152.9 | 153.0 | ||||||
12 | 113.0 | 6.64 s | 112.9 | 6.63 s | 112.3 | 6.62 s | 112.6 | 6.01 s | 112.9 | 6.62 s | 112.8 | 6.63 s |
13 | 19.8 | 0.93 s | 19.8 | 0.93 s | 20.2 | 0.87 s | 20.4 | 0.90 s | 20.4 | 0.91 s | 26.0 | 1.15 s |
14 | 25.1 | 1.10 s | 25.1 | 1.11 s | 26.6 | 1.28 s | 26.1 | 1.34 s | 26.2 | 1.35 s | 20.6 | 1.09 s |
15 | 64.4 | 4.85 s | 71.8 | 4.66 s | 68.5 | 4.53 s | 73.7 | 4.62 s | 64.4 | 4.86 s | 64.4 | 4.86 s |
16 | 66.5 | 3.63 q (6.9) | 66.6 | 3.57 q (6.4) | 58.5 | 3.47 s | ||||||
17 | 15.0 | 1.29 t (6.9) | 15.5 | 1.2 t (6.4) |
1H and 13C NMR data (δ) were measured in chloroform-d at 400 and 100 MHz.
1H and 13C NMR data (δ) were measured in acetone-d6 at 400 and 100 MHz.