1H and 13C NMR data of 10–11 in CD3ODa.
Position | 10 | 11 | ||
---|---|---|---|---|
δ H | δ C | δ H | δ C | |
1 | 4.25 q (6.5) | 80.8 | 3.96 t (6.5) | 85.7 |
2 | 1.38 d (6.5) | 23.8 | 1.61 m, 1.78 m | 30.4 |
3 | 0.85 t (7.5) | 9.2 | ||
1′ | 134.9 | 132.5 | ||
2′ | 6.59 s | 104.2 | 6.55 s | 103.5 |
3′ | 149.4 | 147.8 | ||
4′ | 135.8 | 134.6 | ||
5′ | 149.4 | 147.8 | ||
6′ | 6.59 s | 104.2 | 6.55 s | 103.5 |
3.19 s | 56.1 | 3.18 s | 55.2 | |
3.84 s | 56.3 | 3.83 s | 55.3 | |
3.84 s | 56.3 | 3.83 s | 55.3 |
Signal multiplicity and coupling constants (Hz) are in parentheses. The assignments were based on HSQC, HMBC, and 1H–1H COSY experiments; NMR data were measured using NMR spectrometers operating at 850 MHz for 10 and 800 MHz for 11.