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. 2022 Apr 13;22(5):3343–3358. doi: 10.1021/acs.cgd.2c00153

Table 3. Isomorphous Relationships between NxxCl (this work) and NxxBr:54,84 Comparisons with the Amide-Bridge Reversed Clxx(56) and Brxx(54,83)a.

NxxCl and NxxBr isomer grids
Clxx and Brxx isomer grids
NxxCl space group NxxBr(54) Clxx(56) space group Brxx(54)
NppCl·H2O PbcaP21 NppBr Clpp P21/c Brpp
NpmCl P21/n NpmBr Clmp (Z′ = 4) P1̅ ≠ P Brmp (Z′ = 2)
NpoCl Cc NpoBr Clop Pbca Brop
NmpCl P21C2/c NmpBr Clpm P1̅ ≠ C2/c Brpm
NmmCl P21/nP NmmBr Clmm·H2O P21/c Brmm·H2O
NmoCl P21/cP21/a NmoBr(84) Clom C2/c Brom
NopCl(85) P NopBr Clpo C2/cP Brpo
NomCl P1̅ ≠ C2/c NomBr Clmo P1̅ ≠ P21/c Brmo
NooCl Pbca NooBr Cloo C2/c Broo
a

Isomorphous pairs are highlighted in bold with their common space group in italics. The ≠ symbol is for crystal structures that are not isomorphous; for Clmp and Brmp, Z′ is also noted. Clxx and Brxx are understood as ClxxN and BrxxN but are noted this way in refs (56, 54).