Preparation of O-isopropylidene sugar derivativesa.
| Entry | Sugar | O-Isopropylidene derivatives | Yield (%) |
|---|---|---|---|
| 1 | d-Glucose |
|
95 |
| 2 | d-Ribose |
|
95 |
| 3 | d-Mannose |
|
95 |
| 4 | l-Arabinose |
|
95 |
| 5 | d-Galactose |
|
97 |
Reagents and conditions: 2 : 2 : 1 molar ratios of PS-TPP : I2 : sugar, acetone, RT, 45 min.