Oxidation of sulfides in presence of Fe3O4@BNPs-SiO2–SO3H with H2O2 in ethanol.
| Entry | Substrate | Sulfoxidesa | Sulfonesb | ||||
|---|---|---|---|---|---|---|---|
| Time (min) | Yield (%) | MPref. | Time (min) | Yield (%) | MPref. | ||
| 1 |
|
5 | 94 | 29–3038 | 10 | 92 | 83–8539 |
| 2 |
|
5 | 98 | 69–7138 | 10 | 98 | 125–12626 |
| 3 |
|
2 | 98 | 120–12140 | 10 | 94 | 146–14841 |
| 4 |
|
8 | 98 | 135–13638 | 15 | 96 | 149–15126 |
| 5 |
|
10 | 95 | 13742 | 20 | 95 | 175–17743 |
| 6 |
|
20 | 92 | 16242 | 45 | 96 | 203–20542 |
| 7 |
|
10 | 95 | Oil44 | 25 | 90 | 25–2845 |
| 8 |
|
10 | 94 | 17146 | 30 | 96 | 212–21443 |
| 9 |
|
10 | 96 | 3047 | 20 | 96 | 44–461 |
| 10 |
|
10 | 94 | Oil46 | 20 | 92 | Oil1 |
| 11 |
|
15 | 92 | 151–15248 | 30 | 90 | Oil1 |
| 12 |
|
20 | 92 | 110–11143 | 40 | 90 | 110–11242 |
| 13 |
|
10 | 92 | Oil49 | 25 | 92 | Oil50 |
| 14 |
|
10 | 94 | 20151 | 20 | 94 | 185–18742 |
Reaction conditions: sulfide (1 mmol), H2O2 (0.3 mL), catalyst (0.075 g) at 25 °C in EtOH.
Reaction conditions: sulfide (1 mmol), H2O2 (0.4 mL), catalyst (0.1 g) at 50 °C in EtOH.