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. 2019 Nov 6;9(62):36103–36112. doi: 10.1039/c9ra06221a

Oxidation of sulfides in presence of Fe3O4@BNPs-SiO2–SO3H with H2O2 in ethanol.

Entry Substrate Sulfoxidesa Sulfonesb
Time (min) Yield (%) MPref. Time (min) Yield (%) MPref.
1 graphic file with name c9ra06221a-u1.jpg 5 94 29–3038 10 92 83–8539
2 graphic file with name c9ra06221a-u2.jpg 5 98 69–7138 10 98 125–12626
3 graphic file with name c9ra06221a-u3.jpg 2 98 120–12140 10 94 146–14841
4 graphic file with name c9ra06221a-u4.jpg 8 98 135–13638 15 96 149–15126
5 graphic file with name c9ra06221a-u5.jpg 10 95 13742 20 95 175–17743
6 graphic file with name c9ra06221a-u6.jpg 20 92 16242 45 96 203–20542
7 graphic file with name c9ra06221a-u7.jpg 10 95 Oil44 25 90 25–2845
8 graphic file with name c9ra06221a-u8.jpg 10 94 17146 30 96 212–21443
9 graphic file with name c9ra06221a-u9.jpg 10 96 3047 20 96 44–461
10 graphic file with name c9ra06221a-u10.jpg 10 94 Oil46 20 92 Oil1
11 graphic file with name c9ra06221a-u11.jpg 15 92 151–15248 30 90 Oil1
12 graphic file with name c9ra06221a-u12.jpg 20 92 110–11143 40 90 110–11242
13 graphic file with name c9ra06221a-u13.jpg 10 92 Oil49 25 92 Oil50
14 graphic file with name c9ra06221a-u14.jpg 10 94 20151 20 94 185–18742
a

Reaction conditions: sulfide (1 mmol), H2O2 (0.3 mL), catalyst (0.075 g) at 25 °C in EtOH.

b

Reaction conditions: sulfide (1 mmol), H2O2 (0.4 mL), catalyst (0.1 g) at 50 °C in EtOH.