Free energy barriers of the C–H silylation of a series of substrates (kcal mol−1).
| Substrate | ΔG (TS) | Substrate | ΔG (TS) | Substrate | ΔG (TS) | |||
|---|---|---|---|---|---|---|---|---|
| 1 |
|
21.3 | 2 |
|
17.9 | 3 |
|
16.0 |
| 4 |
|
19.8 | 5 |
|
51.2 | 6 |
|
63.7 |
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