The calculated ΔG^≠ (kcal mol⁻¹), tunneling corrections (κ) and k (M⁻¹ s⁻¹) at 298.15 K in the gas phase.

Reactions	ΔG≠	κ	k Eck
4–O41–H + CH3OO˙	14.5	571.4	8.10 × 104
5–O41–H + CH3OO˙	10.9	48.8	3.36 × 106
11–O41–H + CH3OO˙	10.8	47.1	3.61 × 106
Trolox + CH3OO˙	10.9	63.4	4.11 × 106