Reaction scope of different allylic alcohols and amine^a.

Entry	Allylic alcohols	Nucleophine	T (°C)	Time (h)	Product	Yieldb (%)
1			30	1.5	6a	91
2	4a		30	4	6b	91
3	4a		30	1.5	6c	81
4c	4a		50	26	6d	77
5	4a	CH3SO2NH25e	50	7.5	6e	86
6c	4a	CbzNH25f	30	2	6f	98
7c	4a		50	26	6g	93
8	4a		30	12	6h	98
9		5a	85	53	6i, 6i′	51 (2 : 1)d
10	4b	5b	85	53	6j, 6j′	48 (3 : 1)d
11		5a	50	25	6k	48
12	4c	5b	50	25	6l	42
13		5a	50	8	6m	56
14	4d	5b	50	9	6n	70

^aReaction conditions: 1 mmol allylic alcohols, 2 mmol nucleophile, 3d (0.05 mol% Au), 0.05 mol% AgOTf, 2 mL dioxane, argon atmosphere.

^bIsolated yield.

^c0.2 mol% 3d, 0.2 mol% AgOTf.

^dThe ratio of α-product to γ-product.