Pseudo-first-order and pseudo-second-order kinetic parameters for Sb(iii) and Cd(ii) adsorbed using BC and MnFe2O4–BC in a binary system.
Sample | Ion | Experimental parameters | Pseudo-first order | Pseudo-second order | |||||
---|---|---|---|---|---|---|---|---|---|
pH | q e,exp (mg g−1) | k 1 (min−1) | q e,cal (mg g−1) | R 2 | k 2 (g mg−1 min−1) | q e,cal (mg g−1) | R 2 | ||
BC | Sb(iii) | 7 | 24.60 | 0.0034 | 8.59 | 0.636 | 0.0010 | 25.11 | 0.999 |
BC | Cd(ii) | 7 | 21.60 | 0.0041 | 20.85 | 0.885 | 2 × 10−6 | 21.52 | 0.934 |
MnFe2O4–BC | Sb(iii) | 7 | 62.80 | 0.0035 | 3.55 | 0.551 | 0.0040 | 62.93 | 0.999 |
MnFe2O4–BC | Cd(ii) | 7 | 48.80 | 0.0044 | 3.89 | 0.743 | 0.024 | 48.99 | 0.999 |