Electrochemical data for complexes 1–4 in acetonitrile solutiona.
Complex | Oxidation: E1/2, V (ΔEp, mV) | Reduction: E1/2, V (ΔEp, mV) | ||
---|---|---|---|---|
1 | 1.02 (81) | −1.62 (67) | −1.81 (71) | −2.03 (68) |
2 | 1.00 (90) | −1.62 (76) | −1.81 (78) | −2.04 (73) |
3 | 1.00 (71) | −1.64 (62) | −1.82 (64) | −2.06 (63) |
4 | 1.00 (87) | −1.65 (84) | −1.83 (76) | −2.07 (76) |
V vs. Ag/Ag+; scan rate = 100 mV s−1, ΔEp = |Epa − Epc| while E1/2 = (Epa + Epc)/2.