The donor density (ND) and the film thickness (δ) for the oxide film formed spontaneously on Zn electrode in buffer solutions of pH 9.8 and 9.2 at different temperatures.
T (°C) | N D (cm−3) | δ (Å) |
---|---|---|
pH 9.8 | ||
5 | 2.11 × 1021 | 14.22 |
15 | 1.19 × 1021 | 12.88 |
25 | 1.18 × 1021 | 9.59 |
35 | 1.00 × 1021 | 4.36 |
45 | 3.35 × 1019 | 3.62 |
pH 9.2 | ||
5 | 3.22 × 1020 | 14.49 |
15 | 2.98 × 1020 | 13.01 |
25 | 1.81 × 1020 | 8.44 |
35 | 2.68 × 1018 | 7.72 |
45 | 2.26 × 1018 | 7.11 |